𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction

✍ Scribed by Timothy J. Wallington; William F. Schneider; Trine E. Møgelberg; Ole J. Nielsen; Jens Sehested

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
688 KB
Volume
27
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

A pulse radiolysis system was used to study the kinetics of the reaction of FC(0)Oz radicals with NOz. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ? 0.6) X 10-l' cm3 molecule-' 5-l a t 296 K and 500-1000 mbar pressure of SF6 diluent. A long path length Fourier transform infrared spectrometer was used to investigate the thermal stability of the product FC(0)OzNOz. The rate of thermal decomposition of FC(0)02N02 was independent of the total pressure of Nz diluent over the range 100-700 torr and was fit by the expression k-3 = 6.0 x exp(-14150/T) s-l. The results are discussed in the context of the atmospheric chemistry of FCO, radicals.

📜 SIMILAR VOLUMES

Atmospheric chemistry of acetone: Kineti
Atmospheric chemistry of acetone: Kinetic study of the CH3C(O)CH2O2+NO/NO2 reactions and decomposition of CH3C(O)CH2O2NO2
✍ Jens Sehested; Lene K. Christensen; Ole J. Nielsen; Merete Bilde; Timothy J. Wal 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ

Ab initio study of the mechanism of the
Ab initio study of the mechanism of the atmospheric reaction: NO2 + O3 → NO3 + O2
✍ Julio Peiró-García; Ignacio Nebot-Gil 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 146 KB 👁 1 views

## Abstract The atmospheric reaction NO~2~ + O~3~ → NO~3~ + O~2~ (1) has been investigated theoretically by using the MP2, G2, G2Q, QCISD, QCISD(T), CCSD(T), CASSCF, and CASPT2 methods with various basis sets. The results show that the reaction pathway can be divided in two different parts at the M

Kinetic and mechanistic study of the rea
Kinetic and mechanistic study of the reaction of O(1D) with CF2HBr
✍ R. S. Strekowski; J. M. Nicovich; P. H. Wine 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 166 KB

A laser flash photolysis-resonance fluorescence technique has been employed to investigate the kinetics and mechanism of the reaction of electronically excited oxygen atoms, O( 1 D), with CF 2 HBr. Absolute rate coefficients (k 1 ) for the deactivation of O( 1 D) by CF 2 HBr have been measured as a

The reaction of CH3O2 radicals with NO2
The reaction of CH3O2 radicals with NO2
✍ Hiroyuki Adachi; Norman Basco 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 881 KB

The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc