✍ Scribed by E. Hämeenoja; T. Laitinen; G. Sundholm
No coin nor oath required. For personal study only.
USing a rotating gold ring-lead disc electrode and analysing the deposit on the ring surface with Xray photoelectron spectroscopy, soluble Pb(IV) species were detected during the auodic reaction of the PbS04/Pb02 electrode in sulfuric acid. The Pb(IV) species are not intermediates in the PbOs formation but result from the chemical solubility of PbO*. Measurements of soluble Pb(II) proved that the '*coup de fouet" commonly observed during the discharge of the lead acid battery is due to the oversaturation of Pb(I1) ions.
📜 SIMILAR VOLUMES
A scanning electron microscope investigation of the structure of the reduced Pb/PbS0 4 electrode revealed that lignin prevented the extensive growth of dendritic lead single crystals that occurred in its absence . It was further shown that the smooth surfaced, large diameter dendritic branches, pres
The electrode kinetics of the Pb(II)/Pb(Hg) system has been studied in DMSO and DMSO water mixtures using the farad& Impedance measurements. With the increase of the mole fraction
The kinetics of the processes of reducing tetragonal PbO to Pb has been studied by the linear sweep voltammetry (Isv) technique. It was found that the reduction processes of tetragonal PbO are controlled by OH-ion diffusion through the PbSO, membrane besides the limitation of the nucleation and grow