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The formation of dimers via the rearrangement of a tertiary alicyclic hydroperoxide

โœ Scribed by Ronald D. Bushick; Robert W. Warren


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
140 KB
Volume
14
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


The rearrangement of tertiary alicyclic
โœ Ronald D. Bushick ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

The recent paper by Deno and co-workers' has p-ted us to report the results obtaimd some time ago in our laboratory regarding the rearr vt of tertiary alicyclic hydroperoxides. Rearrangements of aliphatic alkyl hydroperoxides have not been explored in luch depth. Perhaps the most well-known example

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Lithium aluminium hydride reduction of artemisinin produces two unexpected rearrangement products in addition to those reported previously. The structure of the major rearrangement product, a tertiary hydroperoxide, was determined by 2D-NMR and chemical reactions. A mechanism is proposed for this re