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The Wittig Rearrangement of a Tertiary Amine

✍ Scribed by Prof. A. G. Anderson; Dr. M. T. Wills

Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
136 KB
Volume
6
Category
Article
ISSN
0044-8249

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The Sila-Wittig Rearrangement. -The first examples of silicon analogues to the (2,3)-Wittig rearrangements which involve intramolecular migration of an allyl group from an oxygen or nitrogen to silicon are described. The rearrangement is enhanced by a crown ether. Thus the reaction of (I) in the pr