Stereochemistry of the lipoxygenase-cata
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E.J. Corey; Mukund M. Mehrotra
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Article
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1983
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Elsevier Science
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French
β 138 KB
The anaerobic rearrangement of 15-@-HPETE (1) which is effected by the enzyme soybean lipoxygenase -type I leads stereospecifically to the hydroxy-epoxide 2\_ by a cis addition of two oxygens to the 13,14-double bond.