The mechanism of the rearrangement of linoleate hydroperoxides
โ Scribed by Henry W.-S. Chan; Gordon Levett; Jennifer A. Matthew
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 23 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-3084
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
When hydroperoxides are thermally decomposed in the presence of unsaturated fatty acids, dimers are formed in amounts equivalent to the hydroperoxide present. The origin of these dimers has not been shown by any definitive experiment. Radioactively (14C) labeled materials now have been used to deter
The precursor role of hydroperoxides in the formation of aldehydes during linoleate autoxidation was evaluated. Unlabeled propyl linoleate containing each isomer of methyl linoleate [18,18,18-D3] hydroperoxide was autoxidized at 60ยฐC without catalyst or with 10 "~ M copper catalyst. Unlabeled and D3
## Effects of ฮฒ ฮฒ-carotene and retinal on the formation of methyl linoleate hydroperoxides In order to clarify the prooxidative role of carotenoids on the oxidation of unsaturated lipids this study examined the effects of ฮฒ-carotene and its oxidative breakdown product, retinal, on primary oxidatio
The recent paper by Deno and co-workers' has p-ted us to report the results obtaimd some time ago in our laboratory regarding the rearr vt of tertiary alicyclic hydroperoxides. Rearrangements of aliphatic alkyl hydroperoxides have not been explored in luch depth. Perhaps the most well-known example
Incubation experiments in order to study the influence of some parameters in the fluorescence products formation have been carried out. It has been observed a greater efficiency with the relation linoleic acid hydroperoxide:glutathione, 2: 1, and a temperature of 37 "C. The complex formed working wi