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The mechanism of the rearrangement of linoleate hydroperoxides

โœ Scribed by Henry W.-S. Chan; Gordon Levett; Jennifer A. Matthew


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
23 KB
Volume
25
Category
Article
ISSN
0009-3084

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When hydroperoxides are thermally decomposed in the presence of unsaturated fatty acids, dimers are formed in amounts equivalent to the hydroperoxide present. The origin of these dimers has not been shown by any definitive experiment. Radioactively (14C) labeled materials now have been used to deter

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Incubation experiments in order to study the influence of some parameters in the fluorescence products formation have been carried out. It has been observed a greater efficiency with the relation linoleic acid hydroperoxide:glutathione, 2: 1, and a temperature of 37 "C. The complex formed working wi