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The Fischer Indole Synthesis

โœ Scribed by R. S. Downing; P. J. Kunkeler

Publisher
John Wiley and Sons
Year
2003
Weight
48 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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A Novel Abnormal Rearrangement in the Fischer Indole Synthesis. -Application of naltrexone (I) and the tetrahydronaphthylhydrazones (II) gives the expected indole derivatives (III) and an abnormal product (IV) probably via a [3,3] sigmatropic rearrangement. Interestingly, the hydrazone (Ia) lacking