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ChemInform Abstract: A Novel Abnormal Rearrangement in the Fischer Indole Synthesis.

✍ Scribed by H. FUJII; A. MIZUSUNA; R. TANIMURA; H. NAGASE

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel Abnormal Rearrangement in the Fischer Indole Synthesis.

-Application of naltrexone (I) and the tetrahydronaphthylhydrazones (II) gives the expected indole derivatives (III) and an abnormal product (IV) probably via a [3,3] sigmatropic rearrangement. Interestingly, the hydrazone (Ia) lacking the N-alkyl group does not produce (IV). -(FUJII, H.; MIZUSUNA,

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