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ChemInform Abstract: A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis.

โœ Scribed by S. WAGAW; B. H. YANG; S. L. BUCHWALD

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Abnormal Re
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โœ H. FUJII; A. MIZUSUNA; R. TANIMURA; H. NAGASE ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

A Novel Abnormal Rearrangement in the Fischer Indole Synthesis. -Application of naltrexone (I) and the tetrahydronaphthylhydrazones (II) gives the expected indole derivatives (III) and an abnormal product (IV) probably via a [3,3] sigmatropic rearrangement. Interestingly, the hydrazone (Ia) lacking