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Fischer Indole Synthesis of the Indoloquinoline Alkaloid Cryptosanguinolentine.

โœ Scribed by T. Dhanabal; R. Sangeetha; P. S. Mohan


Publisher
John Wiley and Sons
Year
2005
Weight
13 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Total Synthesis of the Indole Alkaloid V
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The tetrahedrane framework with R=tBu and the octabisvalene framework with R = CH3 presumably form because of steric reasons. Whereas the hydrocarbon 2 is highly strained, the arrangement in 1 is largely strain-free, based on the intermolecular contact distances. With other residues R the occurrenc