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The First Two Novel Metallomacrocycles Constructed from Cubane-Like Cu4I4 Cluster Units and Ditopic Diamines

✍ Scribed by Rui-Hu Wang; Mao-Chun Hong; Jun-Hua Luo; Rong Cao; Jia-Bao Weng


Book ID
101350723
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
90 KB
Volume
2002
Category
Article
ISSN
1434-1948

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The reaction of CuI with cinchonine (an organic donor-acceptor chromophore) afforded a homochiral 3D diamondoid network [Cu 4 I 4 (cinchonine) 2 ] n (1) containing a cubane cluster (Cu 4 I 4 ) as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a c