✦ LIBER ✦
The First Homochiral Diamond-Like Coordination Polymer Containing Cubane Cluster (Cu4I4) as Connecting Node and Cinchonine as Donor-Acceptor (or Push-Pull Electronic Effect) Building Block
✍ Scribed by Guo-Xi WANG; Ren-Gen XIONG
- Book ID
- 102102861
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 111 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0256-7660
No coin nor oath required. For personal study only.
✦ Synopsis
The reaction of CuI with cinchonine (an organic donor-acceptor chromophore) afforded a homochiral 3D diamondoid network [Cu 4 I 4 (cinchonine) 2 ] n (1) containing a cubane cluster (Cu 4 I 4 ) as a connecting node. This is the first homochiral coordination polymer with diamondoid nets containing a cluster as a connecting note. Its thermal stability and solid state optical properties such as fluorescence, circular dichroism and second-harmonic generation response were also reported.