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The synthesis and crystal structure of a novel cubane-like tungsten copper sulfur cluster [W3CuS4]·[S2P(OC2H5)2]3·I·μ2-CH3COO·CH3CN

✍ Scribed by Wu Xintao; Zhan Huqiang; Zheng Yifan; Lu Jiaxi


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
296 KB
Volume
197
Category
Article
ISSN
0022-2860

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✍ Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and N