✦ LIBER ✦

The First Negishi Cross-Coupling Reaction of Two Alkyl Centers Utilizing a Pd—N-Heterocyclic Carbene (NHC) Catalyst.

✍ Scribed by Niloufar Hadei; Eric Assen B. Kantchev; Christopher J. O'Brien; Michael G. Organ

Publisher: John Wiley and Sons
Year: 2005
Weight: 25 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200552047

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Room-Temperature Negishi Cross-Coupling

Room-Temperature Negishi Cross-Coupling of Unactivated Alkyl Bromides with Alkyl Organozinc Reagents Utilizing a Pd/N-Heterocyclic Carbene Catalyst.

✍ Niloufar Hadei; Eric Assen B. Kantchev; Christopher J. O'Brien; Michael G. Organ 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

A User-Friendly, All-Purpose Pd-NHC (NHC

A User-Friendly, All-Purpose Pd-NHC (NHC: N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst.

✍ Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. K 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 43 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

A User-Friendly, All-Purpose Pd–NHC (NHC

A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst

✍ Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. K 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 1 views

## Abstract We have developed the first user‐friendly Negishi protocol capable of routinely cross‐coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, well‐defined precatalyst PEPPSI‐IPr (**1**; PEPPSI=pyridine‐enhanced precatalyst prepar

Cover Picture: Easily Prepared Air- and

Cover Picture: Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction / A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst (Chem. Eur. J. 18/2006)

✍ Christopher J. O'Brien; Eric Assen B. Kantchev; Cory Valente; Niloufar Hadei; Gr 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 380 KB 👁 1 views

Diastereoselective Metal-Catalyzed [4 +

Diastereoselective Metal-Catalyzed [4 + 2 + 2] Carbocyclization Reactions Utilizing a Rhodium N-Heterocyclic Carbene (NHC) Complex: The First Example of a Rhodium NHC-Catalyzed [m + n + o] Carbocyclization.

✍ P. Andrew Evans; Erich W. Baum; Aleem N. Fazal; Maren Pink 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 22 KB 👁 1 views