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A User-Friendly, All-Purpose Pd-NHC (NHC: N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst.

✍ Scribed by Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. Kantchev; Christopher J. O'Brien; Cory Valente

Publisher
John Wiley and Sons
Year
2006
Weight
43 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

A User-Friendly, All-Purpose Pd–NHC (NHC
A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst
✍ Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. K 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 1 views

## Abstract We have developed the first user‐friendly Negishi protocol capable of routinely cross‐coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, well‐defined precatalyst PEPPSI‐IPr (**1**; PEPPSI=pyridine‐enhanced precatalyst prepar

Cover Picture: Easily Prepared Air- and
Cover Picture: Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction / A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst (Chem. Eur. J. 18/2006)
✍ Christopher J. O'Brien; Eric Assen B. Kantchev; Cory Valente; Niloufar Hadei; Gr 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 380 KB 👁 1 views