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Cover Picture: Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction / A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst (Chem. Eur. J. 18/2006)

✍ Scribed by Christopher J. O'Brien; Eric Assen B. Kantchev; Cory Valente; Niloufar Hadei; Gregory A. Chass; Alan Lough; Alan C. Hopkinson; Michael G. Organ; Stephanie Avola; Igor Dubovyk

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
380 KB
Volume
12
Category
Article
ISSN
0947-6539

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A User-Friendly, All-Purpose Pd-NHC (NHC
A User-Friendly, All-Purpose Pd-NHC (NHC: N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst.
✍ Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. K 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 43 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

A User-Friendly, All-Purpose Pd–NHC (NHC
A User-Friendly, All-Purpose Pd–NHC (NHC=N-Heterocyclic Carbene) Precatalyst for the Negishi Reaction: A Step Towards a Universal Cross-Coupling Catalyst
✍ Michael G. Organ; Stephanie Avola; Igor Dubovyk; Niloufar Hadei; Eric Assen B. K 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 253 KB 👁 1 views

## Abstract We have developed the first user‐friendly Negishi protocol capable of routinely cross‐coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, well‐defined precatalyst PEPPSI‐IPr (**1**; PEPPSI=pyridine‐enhanced precatalyst prepar