𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The First Mononuclear η2-C60 Complex of Osmium: Synthesis and X-ray Crystal Structure of [(η2-C60)Os(CO)(tBuNC)(PPh3)2]

✍ Scribed by Alexander V. Usatov; Ekaterina V. Martynova; Ivan S. Neretin; Yuri L. Slovokhotov; Alexander S. Peregudov; Yurii N. Novikov

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
113 KB
Volume
2003
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis, Characterization and Electroc
Synthesis, Characterization and Electrochemical Properties of Optically Active [60]Fullerene Organotransition Metal Complexes mer-[(η2-C60)M(CO)3{(−)-DIOP}] (M = Mo, W), mer-[(η2-C60)M(CO)3{(+)-DIOP}] (M = Mo, W) and [(η2-C60)M{(−)-DIOP}] (M = Pd, Pt) − Crystal Structure of [(η2-C60)Pt{(−)-DIOP}]
✍ Li-Cheng Song; Peng-Chong Liu; Jin-Ting Liu; Fu-Hai Su; Guang-Feng Wang; Qing-Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP

Titanium(0) Arene Complexes: Synthesis a
Titanium(0) Arene Complexes: Synthesis and X-ray Crystal Structure of [η6-C10H8Ti{tBuSi(CH2PMe2)3}]
✍ Thomas G. Gardner; Prof. Dr. Gregory S. Girolami 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 520 KB

To a stirred solution of [TiC13(trimpsi)(thf)] (3.90 g, 7.27 mmol) in tetrahydrofuran (50 mL) at -78°C was added naphthalenesodium (150 mL, 0.145 M in THF, 21.8 mmol). A red-purple solution formed immediately. The solution was warmed to room temperature slowly, and the solvent was removed in vacuum.