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Synthesis, Characterization and Properties of Transition Metal Pd/Pt [60]Fullerene Complexes Containing Phosphane Ligands − Crystal Structure of [Pd(η2-C60){Ph2PCH2(CH2OCH2)2CH2PPh2}]

✍ Scribed by Li-Cheng Song; Guang-Ao Yu; Hu-Ting Wang; Fu-Hai Su; Qing-Mei Hu; Ying-Lin Song; Ya-Chen Gao

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
186 KB
Volume
2004
Category
Article
ISSN
1434-1948

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Synthesis, Characterization and Electroc
Synthesis, Characterization and Electrochemical Properties of Optically Active [60]Fullerene Organotransition Metal Complexes mer-[(η2-C60)M(CO)3{(−)-DIOP}] (M = Mo, W), mer-[(η2-C60)M(CO)3{(+)-DIOP}] (M = Mo, W) and [(η2-C60)M{(−)-DIOP}] (M = Pd, Pt) − Crystal Structure of [(η2-C60)Pt{(−)-DIOP}]
✍ Li-Cheng Song; Peng-Chong Liu; Jin-Ting Liu; Fu-Hai Su; Guang-Feng Wang; Qing-Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP