Synthesis and Characterization of Pentaarylated [60]Fullerene Coordinated Complexes [(η2-Ar5C60H)M(PPh3)2] (M = Pt, Pd) and an ab initio Study on Their Isomerism

Synthesis, Characterization and Electroc

Synthesis, Characterization and Electrochemical Properties of Optically Active [60]Fullerene Organotransition Metal Complexes mer-[(η2-C60)M(CO)3{(−)-DIOP}] (M = Mo, W), mer-[(η2-C60)M(CO)3{(+)-DIOP}] (M = Mo, W) and [(η2-C60)M{(−)-DIOP}] (M = Pd, Pt) − Crystal Structure of [(η2-C60)Pt{(−)-DIOP}]

✍ Li-Cheng Song; Peng-Chong Liu; Jin-Ting Liu; Fu-Hai Su; Guang-Feng Wang; Qing-Me 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 245 KB

## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (−)‐DIOP ligand [DIOP = 2,3‐__O__,__O′__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(η^2^‐C~60~)M(CO)~3~{(−)‐DIOP