The Fermi doublet V2−V3 + V4 of CH3CN as a probe of molecular interactions
✍ Scribed by José Fernández Bertrán; Boris La Serna; Klaus Doerffel; Klaus Dathe; Gunther Kabish
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 404 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0022-2860
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Excess molar enthalpies at the temperature 298.15 K were measured for CH2)n-2CH3}, (n = 10, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-Chao, UNIFAC I, and UNIFAC II models.
Almost 300 new rotational transitions within the fundamental vibrational level v 10 = 1 of propyne have been measured in selected regions between 495 and 925 GHz spanning the quantum numbers 28 ≤ J ≤ 54 and 0 ≤ K ≤ 16. The accuracies are mostly between 10 and 20 kHz. In addition, the J = 4 and 5 tra
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