✦ LIBER ✦

The v10=1 Level of Propyne, H3CCCH, and Its Interactions with v9=1 and v10=2

✍ Scribed by H.S.P Müller; P Pracna; V.-M Horneman

Publisher: Elsevier Science
Year: 2002
Tongue: English
Weight: 175 KB
Volume: 216
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.2002.8661

No coin nor oath required. For personal study only.

✦ Synopsis

Almost 300 new rotational transitions within the fundamental vibrational level v 10 = 1 of propyne have been measured in selected regions between 495 and 925 GHz spanning the quantum numbers 28 ≤ J ≤ 54 and 0 ≤ K ≤ 16. The accuracies are mostly between 10 and 20 kHz. In addition, the J = 4 and 5 transitions near 85 and 103 GHz have been remeasured. Simultaneous analyses with refined rovibrational data have been performed, showing that even this lowest and seemingly isolated vibrational level needs a global treatment when high K transitions are involved. The global model with the v 10 = 1 level coupled to the next higher cluster of levels, v 10 = 2/v 9 = 1, by Fermi and Coriolis resonances is necessary for a quantitative reproduction of both the rovibrational and rotational data within their experimental uncertainties. Included are also improved ground state spectroscopic parameters from a fit of previous pure rotational data and k = 3 ground state combination loops as well as additional data obtained in course of the present study.

📜 SIMILAR VOLUMES

Excess molar volumes of {x(C4H9)2O + (1−

Excess molar volumes of {x(C4H9)2O + (1−x)H(CH2)v(OCH2CH2)3OH} (v= 1, 2, and 4) at the temperature 298.15 K

✍ Amalendu Pal; Wazir Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 390 KB

The excess molar volumes V E m of binary mixtures of {x(C4H9)2O + (1-x)H(CH2)n (OCH2CH2)3OH} for n=1, 2, and 4 have been measured as a function of mole fraction x using a continuous-dilution dilatometer at T=298.15 K. The V E m decreases in magnitude as the alkyl chain length of the alkoxyethanol in

ChemInform Abstract: Synthesis and Cryst

ChemInform Abstract: Synthesis and Crystal Structure of a Triprotonated Decavanadate, [(C6H5CH2)(CH3)3N] 3 [H3V10O28]·3H2O.

✍ Anindita Dewan; Dilip K. Kakati; Birinchi K. Das 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 21 KB 👁 3 views

Synthesis of [2H, 13C] and [14C] labeled

Synthesis of [2H, 13C] and [14C] labeled vasopressin V1a/V2 receptor antagonist RWJ-676070 and its stable labeled N-des-benzoyl metabolite

✍ Yong Gong; David C. Hoerr; Larry E. Weaner; Ronghui Lin 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 French ⚖ 141 KB

Isothermal compressibilities and excess

Isothermal compressibilities and excess molar volumes of {xCH3C(CH3)2CH2CH(CH3)CH3 + (1 - x)cis-C10H18} at the temperature T = 298.15 K; and of {xCH3C(CH3)2CH2CH(CH3)CH3 + (1 - x)trans-C10H18} at T = 298.15 K and 318.15 K

✍ K. Chyliński 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 187 KB

Cage opening of 1,2-(CH2OH)2-closo-1,2-C

Cage opening of 1,2-(CH2OH)2-closo-1,2-C2B10H10 with 2-(aminomethyl)-pyridine: synthesis and structure of a cobalt salt of functionalized nido-C2B9H10 mono anion

✍ Aderemi R. Oki; Blanca Gilbes; Faina Tarasyuk; Thomas J. Emge 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 338 KB 👁 1 views

## Abstract The reaction of 1,2‐(CH~2~OH)~2~‐__closo__‐1,2‐C~2~B~10~ H~10~ carborane with 2‐(aminomethyl)‐pyridine in methylene chloride at room temperature led to the partial cage degradation of the __closo__ carborane and its conversion to the __nido__ derivative. The addition of cobalt chloride

Excess molar volumes and excess partial

Excess molar volumes and excess partial molar volumes of {xC6H5CH3+ (1−x)H(CH2)v(OCH2CH2)3OH} (v= 1,2, and 4) at the temperature 298.15 K

✍ A. Pal; W. Singh 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 402 KB

The excess molar volumes V E m for binary liquid mixtures of {xC6H5CH3 + (1-x)H(CH2)n(OCH2CH2)3OH} for n = 1, 2, and 4 have been measured using a continuous-dilution dilatometer over the entire mole fraction x range at T = 298.15 K. The excess volume curves for these three mixtures are sigmoid shape