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The faulted structures of [WCl2(PhC2Ph)(CH2=CH2)(PMe3)2] and [WCl2(PhC2Ph)2(PMe3)2]

✍ Scribed by Clark, G. R. ;Nielson, A. J. ;Rickard, C. E. F. ;Rae, A. D.


Book ID
114510398
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
689 KB
Volume
49
Category
Article
ISSN
0108-2701

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A chain copolymer from WCl2(PMe2Ph)4 and
✍ Helmut Rothfuss; Kirsten Folting; Kenneth G. Caulton πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 878 KB

## A combination of WCl,(PMe,Ph), and [TlOCH,CF,], crystallize from hexane solution as a I:1 material whose structure shows it to be an alternating chain copolymer. The link between the W-and Tl-containing monomers IS composed of weak Tl/Cl interactions between otherwise not significantly distorte