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Preparation of (PME3)3HRu(μ-CH2PME2)2RuH(PMe3)3 and Ru(η1-CCH(CH2)3)(PMe3)4H

✍ Scribed by Christof E. Graimann; Malcolm L.H. Green


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
159 KB
Volume
275
Category
Article
ISSN
0022-328X

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop