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Activation of Aryl Germanium(II) Chlorides by [Mo(PMe3)6] and [W(η2-CH2PMe2)H(PMe3)4]: A New Route to Metal–Germanium Triple Bonds

✍ Scribed by Alexander C. Filippou; Nils Weidemann; Athanassios I. Philippopoulos; Gregor Schnakenburg


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
145 KB
Volume
45
Category
Article
ISSN
0044-8249

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Activation of Aryl Germanium(II) Chlorid
✍ Alexander C. Filippou; Nils Weidemann; Athanassios I. Philippopoulos; Gregor Sch 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop