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Heteronuclear unbridged molybdenum-tungsten quadruply bonded complexes. Preparation and characterization of Cl2(PMe2Ph)2Mo-WCl2(PMe2Ph)(PPh3), Cl2(PMe2Ph)(PPh3)Mo-WCl2(PMe2Ph)2 and Mo-WCl4(PMe2Ph)4

โœ Scribed by Cotton, F. Albert; Falvello, Larry R.; James, Chris A.; Luck, Rudy L.

Book ID
127155319
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
600 KB
Volume
29
Category
Article
ISSN
0020-1669

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A chain copolymer from WCl2(PMe2Ph)4 and
A chain copolymer from WCl2(PMe2Ph)4 and [TlOCH2CF3]4
โœ Helmut Rothfuss; Kirsten Folting; Kenneth G. Caulton ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 878 KB

## A combination of WCl,(PMe,Ph), and [TlOCH,CF,], crystallize from hexane solution as a I:1 material whose structure shows it to be an alternating chain copolymer. The link between the W-and Tl-containing monomers IS composed of weak Tl/Cl interactions between otherwise not significantly distorte