The Facile Oxidation of Thiols to Disulfides with Bis(2,2′-Bipyridyl) Copper-(II) Permanganate
✍ Scribed by Firouzabadi, H.; Naderi, M.; Sardarian, A.; Vessal, B.
- Book ID
- 120091728
- Publisher
- Taylor and Francis Group
- Year
- 1983
- Tongue
- English
- Weight
- 140 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0039-7911
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📜 SIMILAR VOLUMES
Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi
BBCP was prepared by the reported method . The preparation, purification, and specification of the substituted benzyl alcohols and ␣,␣-dideuteriobenzyl alcohol (PhCD 2 OH) have been described earlier . Acetic acid was refluxed with chromic oxide and acetic anhydride for 6 h and then fractionated. Pe