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The Exotic Potential Curve of the 31ΠgState of K2by Optical–Optical Double-Resonance Spectroscopy

✍ Scribed by J.T. Kim; H. Wang; J.T. Bahns; W.C. Stwalley

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
169 KB
Volume
181
Category
Article
ISSN
0022-2852

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✦ Synopsis

The Rydberg-Klein-Rees potential curve of the 3 1 P g state which covers the internuclear distance from 3.59926 to 6.76571 A ˚is constructed from the experimentally determined B £ and G(£) values. The predicted exotic shape (change in slope outside Ç5.7 A ˚) agrees with the experimental results. The dissociation energy of this state which dissociates to the K(4s) / K(5p) atomic asymptotic limit is determined to be 2731.292 { 0.085 cm 01 .

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