A flow microcalorimeter of the Picker design was used to measure excess molar enthalpies H E m at the temperature 298.15 K over the whole composition range of several binary liquid mixtures formed from an alkanoic acid and either n-heptane, or cyclohexane, or benzene. The alkanoic acids selected wer
The excess molar enthalpies of (N-methyl-2-pyrrolidinone  +  mono-, or di-, or trichlorobenzene) atT =  298.15 K
✍ Scribed by Trevor M. Letcher; Urszula Domańska; ; Joanna Łachwa
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 128 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
Excess molar enthalpies H E m at T = 298.15 K are reported for (N -methyl-2pyrrolidinone + chlorobenzene, or 1,2-dichlorobenzene, or 1,3-dichlorobenzene, or 1,2,4,-trichlorobenzene). The values of H E m were obtained by using the flow calorimetric method. All the mixtures, over the whole composition range, are formed exothermically. The H E m results are discussed in terms of the NRTL and UNIQUAC models.
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