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Excess molar enthalpies of (acetonitrile  +  butan-2-one) and (methanol +  acetonitrile  +  butan-2-one) atT =  298.15 K

✍ Scribed by Kazuhiro Tamura; Masamitsu Watanabe; Satoshi Tsuchiya; Toshiro Yamada

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
140 KB
Volume
33
Category
Article
ISSN
0021-9614

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✦ Synopsis

The excess molar enthalpies of (acetonitrile + butan-2-one) and (methanol + acetonitrile + butan-2-one) were measured at T = 298.15 K and atmospheric pressure using a flow microcalorimeter. The experimental results are correlated with polynomial equations and compared with those calculated from associated solution models taking account into selfassociation of methanol and acetonitrile as well as solvation between unlike molecules and a non-polar interaction term.

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