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Excess molar enthalpies for (butanenitrile  +  an aromatic hydrocarbon) atT =  298.15 K

✍ Scribed by Trevor M. Letcher; Pavan K. Naicker


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
119 KB
Volume
32
Category
Article
ISSN
0021-9614

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✦ Synopsis


The excess molar enthalpies for (butanenitrile + benzene, or methylbenzene, or 1,2-dimethylbenzene, or 1,3-dimethylbenzene, or 1,4-dimethylbenzene, 1,3,5trimethylbenzene, or ethylbenzene) have been determined at T = 298.15 K. The excess molar enthalpies ranged from a minimum of -57 J β€’ mol -1 for benzene to a maximum of 248 J β€’ mol -1 for 1,3,5-trimethylbenzene. The Redlich-Kister equation, the NRTL and UNIQUAC models were used to correlate the data. The results indicate a relatively strong association between butanenitrile and each of the aromatic compounds, decreasing with increasing methyl substitution on the benzene moiety.


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