The entropy of hydration of simple hydrophobic solutes
β Scribed by Michael E. Paulaitis; Henry S. Ashbaugh; Shekhar Garde
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 750 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0301-4622
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π SIMILAR VOLUMES
Liquid state computer simulation ti reported on a dllutc aqueous solution of formamide at 25Β°C. Analysis of the results reveals essential characteristics of hydrophilic and hydrophobic hydration in the fust shell of the hydration complex.
The complex dielectric permittivity for the series of aqueous allyl-substituted ammonium salt solutions is investigated in microwave range (13-25 GHz) in a wide range of salt concentrations. The measurements were made at 298 K for diallylammonium and diallylmethylammonium trifluoroacetates and in th
The entropy fluctuation in liquids and solutions is most conveniently normalized to the coarse-grained volume. Hence, ((AS~V) 2 ) = RCp/V 2 and <(aS/VΓaN/N)> = Rr~p/Vm. It was shown to be useful if the response functions, Cp, K r and ap, and the fluctuations derived from them, were discussed separat