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Entropy of hydrophobic hydration: a new statistical mechanical formulation

โœ Scribed by Themis Lazaridis; Michael E. Paulaitis


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
398 KB
Volume
83
Category
Article
ISSN
0378-3812

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## Abstract A new formulation of the Lindemann mechanism of unimolecular reactions in gaseous phase is presented, without the use of steady state hypothesis. It is hereby shown that the nature of applicability of steady state hypothesis in the regime of high reactant gas pressure is different from