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The enantioselective conversion of ortho-substituted benzoic acids to chiral cyclohexane derivatives

✍ Scribed by Arthur G. Schultz; Padmanabhan Sundararaman; Mark Macielag; Frank P. Lavieri; Martha Welch


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
197 KB
Volume
26
Category
Article
ISSN
0040-4039

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Conversion of oleic acid to 17- and 18-s
✍ Augustin, Kim E. ;SchΓ€fer, Hans J. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 402 KB

## Abstract Stearolic acid (2) was prepared from oleic acid (1) and converted to 4, 5, and 7 by way of the β€žacetylene zipper”︁ reaction. Compounds 5 and 7 were transformed to the (Ο‰ – 1) ketones 8 and 9 and dimerized by way of the Glaser coupling reaction to 11 and 12. At daylight, 12 polymerizes t