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ChemInform Abstract: Influence of the Nature of Chiral Auxiliaries on the Diastereoselective Hydrogenation of ortho-Substituted Benzoic Acid Derivatives.

✍ Scribed by Michele Besson; Pierre Gallezot; Samuel Neto; Catherine Pinel

Publisher: John Wiley and Sons
Year: 2000
Weight: 29 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200039053

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A number of 2,3-epoxy alcohol derivatives (1-16), obtained either as racemates or through the Sharpless asymmetric epoxidation reaction, were studied on a Chiralcel OD column. Nearly all compounds exhibit good enantioselective resolution on this chiral support. The order of elution of enantiomers is