๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The Electrostatic Interaction of a Charged Particle with a Surface: The Effect of Surface Charge Rearrangement

โœ Scribed by Heng-Kwong Tsao; Yu-Jane Sheng


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
86 KB
Volume
233
Category
Article
ISSN
0021-9797

No coin nor oath required. For personal study only.

โœฆ Synopsis


In this paper we investigate the electric interaction between a charged particle and a surface in which the charged ions are capable of moving in response to the electric potential disturbance caused by the approach of the charged particle. Such surfaces include ionic surfactants distributed in air-water interface and charged lipids in bilayer membranes. On the basis of the mean field theory, the free energy of the system, which includes the electrostatic internal energy and the entropy of the mobile ions and surface ions, can be written down. The surface charge-potential relation is then derived by the calculus of variation. When the potential disturbance is small enough, a linear charge regulation model is obtained. The interaction energy associated with a long rod parallel to the interface is studied and an analytical expression is obtained. When a rod approaches an oppositely charged surface, the interaction can change from attraction to repulsion, depending on the ratio of the characteristic regulation length to the Debye length. At low surface charge density, the surface behaves as under the condition of constant charge density and acts as that of constant potential for high enough charge density.


๐Ÿ“œ SIMILAR VOLUMES


The Electrostatic Interaction Force betw
โœ Jyh-Ping Hsu; Yung-Chih Kuo ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 145 KB

## charge-regulation phenomenon. Ninham and Parsegian The electrostatic interaction force between a charge-regulated ( 2 ) initiated the analysis by proposing a model in which particle covered by an ion-penetrable charged membrane and a the surface of an entity contains single ionizable funcrigid

Electrostatic Interaction between a Sphe
โœ Hiroyuki Ohshima ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 271 KB

The electrostatic interaction between two spheres of con-An explicit exact analytic expression for the energy of the elecsiderably different sizes can be approximated as the plate/ trostatic interaction between a platelike particle 1 and a spherical sphere interaction. The electrostatic interaction

Electrostatic Interactions of a String-L
โœ Heng-Kwong Tsao ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 285 KB

The electrostatic interactions for a string-like particle with a tion efficiency . charged plate are investigated on the basis of the Poisson-Boltz-The extensive investigations on the electrical double-layer mann equation under the Debye-Hu ยจckel approximation. During interactions were focused on th

The Electrostatic Interaction Between Tw
โœ Ming-Tsan Tseng; Jyh-Ping Hsu ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 169 KB

The electrostatic interaction between two parallel, planar charged surfaces with periodic mixed boundary conditions is analyzed. The Poisson-Boltzmann equation (PBE) governing the powhere C ร… ef/kT, x ร… kx หœ, y ร… ky หœ, z ร… kz หœ, and k 2 ร… (e 2 อš i z 2 i n i 0 )/ tential distribution of the system un