The electronic absorption spectrum of the trifluoromethyl radical
โ Scribed by N. Basco; F.G.M. Hathorn
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 317 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Bands of the following well-known systems were ob-In~aur. Ju\rus-l.leb$-Uni\~r\llrit. Gicswn, \Vcw Germ\_m) \_ served in absorption in the above experiments: free radical spectra have been obtained together with a spectrum which appears to correspond to that of the CNO free radical discussed above.
The electronic spectrum of CrO\* 2-is identical to that of &InO; exceptfor &I energy inversion of the 3rd nnd 4th band systems. A very we&lowest-energy band, the authenticity of whfch has been in debate for bln0;. is unambiguously present in CrO'-. The intense (E, z 104) 55 560 cm-l band of CrOz-and
An absorption spectrum near 4800 A was observed from flash photolysis of a mixture of Cr(CC& + hfo(CO& vapours, which is tentatively assigned to the CrMo molecule.
The 0 -1 band (4271.3 ร ) of the B 2 โบ ฯฉ -X 2 2 โธ 3/ 2 transition, the 0 -6 band (4275 ร ) of the H 2 โธ 3/ 2 -X 2 2 โธ 3/ 2 transition, the 0 -0 band (3776.2 ร ) of the B 2 โบ ฯฉ -X 1 2 โธ 1/ 2 transition, and the 2-0 (3251.3 ร ) as well as the 3-0 (3194.2 ร ) bands of the C 2 โบ ฯช -X 1 2 โธ 1/ 2 transition of