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The electronic absorption spectrum of chromate ion

โœ Scribed by L.W. Johnson; S.P. McGlynn


Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
238 KB
Volume
7
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The electronic spectrum of CrO* 2-is identical to that of &InO; exceptfor &I energy inversion of the 3rd nnd 4th band systems. A very we&lowest-energy band, the authenticity of whfch has been in debate for bln0;. is unambiguously present in CrO'-. The intense (E, z 104) 55 560 cm-l band of CrOz-and the correlatmg 32 600 cm-l band of MnO.? exhibl s srgnnlflcant decrease of intensity in the solid state; the + . . . corresponding transitions presumnhl?_ possess -"big orbit" character.


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Single crystals of copper formate tetrahydrate were gown at room temperature. Spectra in the near infrared at room temperature and in the visible at room and liquid air temperatures were recorded on a Unicam SF'-7C0 spectraphotometer and Hilger medium quastz spectrograph respectively. l%e observed a