The electrochemical reduction of dilute aqueous solutions of monobutyltin containing nitrate and chloride electrolytes has been examined at mercury electrodes using the techniques of direct current polarography, cyclic voltammetry, differential pulse polarography and differential pulse voltammetry.
The electrochemistry of dibutyltin at mercury electrodes in aqueous media
β Scribed by Nicholas J. Turoczy; Rodney J. Carter; Alan M. Bond
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 576 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1040-0397
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reduction of Mn\*+ has been studied in formamide, dimethyl formamide and acetonitrile Mn2+ gives well defined current/voltage curves in aqueous and non-aqueous media. The kinetic parameters K, and a have been calculated by means of Matsuda's and Gellings' theoretical treatments in water, aqueous
The reduction of indium at the dropping mercury electrode in sodium nitrate and sodium perchlorate solutions has been studied. The reduction is diffusion controlled but the process is not reversible. The kinetic parameters a and k, have been calculated by Gelling's method. The k, was found to be of
The analysis of polarographic and coulometric results shows that the overall reduction mechanism of chlorobenzenesulphonamide derivatives occurs with the cleavage of the C-Cl bond followed by the reduction of the benzenesulphonamide involving the S-N bond breaking. However, theg, ,2 values fit the s