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The electrochemical behaviour of the nickel(II) ion at the dropping mercury electrode in the presence of some complexing agents—IV

✍ Scribed by D.R. Crow

Book ID
107749325
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
538 KB
Volume
29
Category
Article
ISSN
0013-4686

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✍ P.K. Aggarwal; D.R. Crow 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 510 KB

The polarographic characteristics of the nickel(H) ion in the presence of six heterocyclic species are reported; although slight mechanistic differences exist in reduction behaviour between members of the pyridine and pyrazole series, they share the common feature that the rate-determining step invo

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✍ D.R. Crow 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 519 KB

A new method is described which is applicable to the determination of overall formation constants of complexes which show irreversible reduction at the dropping mercury electrode. Values of the formation constants for the six species produced by the interaction between the NiZ+ ion and pyramle are r