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The effects of ZnGa2O4 formation on structural and optical properties of ZnO:Ga powders

✍ Scribed by Agnaldo de Souza Gonçalves; Sergio Antonio Marques de Lima; Marian Rosaly Davolos; Selma Gutierrez Antônio; Carlos de Oliveira Paiva-Santos


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
197 KB
Volume
179
Category
Article
ISSN
0022-4596

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✦ Synopsis


Gallium-doped zinc oxide (ZnO:Ga 1, 2, 3, 4 and 5 at%) samples were prepared in powder form by modifying the Pechini method. The formation of zinc gallate (ZnGa 2 O 4 ) with the spinel crystal structure was observed even in ZnO:Ga 1 at% by X-ray diffraction. The presence of ZnGa 2 O 4 in ZnO:Ga samples was also evidenced by luminescence spectroscopy through its blue emission at 430 nm, assigned to charge transfer between Ga 3+ at regular octahedral symmetry and its surrounding O 2À ions. The amount of ZnGa 2 O 4 increases as the dopant concentration increases, as observed by the quantitative phase analysis by the Rietveld method.


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