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The Effect of Solvent Polarity on the Product Distribution in the Reaction of Singlet Oxygen with Enolic Tautomers of 1-(2‘,4‘,6‘-Trialkylphenyl)-2-methyl 1,3-Diketones

✍ Scribed by Yoshioka, Michikazu; Sakuma, Yuumi; Saito, Masaichi


Book ID
126231235
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
104 KB
Volume
64
Category
Article
ISSN
0022-3263

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The Reaction of Singlet Oxygen with 1,3-
✍ Charles W. Jefford; Danielle Jaggi; John Boukouvalas; Shigeo Kohmoto; Gérald Ber 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 441 KB

## Abstract The dye‐sensitized photo‐oxygenation of 1,3‐dimethylindole in the presence of aldehydes initially generates a zwitterionic peroxide which condenses with the carbonyl function to give the corresponding __cis__‐fused 1,2,4‐trioxanes. Acetaldehyde gives a pair of diastereomers, one of whos