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Reaction of singlet oxygen with enol ethers in the presence of acetaldehyde. Formation of 1,2,4-trioxanes

✍ Scribed by Jefford, Charles W.; Kohmoto, Shigeo; Boukouvalas, John; Burger, Ulrich

Book ID
126040883
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
291 KB
Volume
105
Category
Article
ISSN
0002-7863

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The Reaction of Singlet Oxygen with 1,3-
The Reaction of Singlet Oxygen with 1,3-Dimethylindole in the Presence of Aldehydes. Formation of 1,2,4-Trioxanes
✍ Charles W. Jefford; Danielle Jaggi; John Boukouvalas; Shigeo Kohmoto; Gérald Ber 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 441 KB

## Abstract The dye‐sensitized photo‐oxygenation of 1,3‐dimethylindole in the presence of aldehydes initially generates a zwitterionic peroxide which condenses with the carbonyl function to give the corresponding __cis__‐fused 1,2,4‐trioxanes. Acetaldehyde gives a pair of diastereomers, one of whos