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The effect of protonation on [Mn(IV)(μ2-O)]2complexes

✍ Scribed by Michael J. Baldwin; Andrew Gelasco; Vincent L. Pecoraro


Publisher
Springer
Year
1993
Tongue
English
Weight
553 KB
Volume
38
Category
Article
ISSN
0166-8595

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✦ Synopsis


The series of complexes [Mn(IV)(X-SALPN)(,u2-O


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Procedures for the conversion of μ2S→μ2O
✍ Liu Qiu-Tian; Jiaxi Lu; A. Geoffrey Sykes 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 376 KB

The reaction of trinuclear MO(N), incomplete cuboidal complexes [Mo,S,(H,O),]~+, [Mo,OS,(H,O),]~+ and Fro,W,W,W4+ with BH.,-in aqueous HCl solutions results in the conversion of core ligands A-S to h-0. In combination with Dowex cation-exchange chromatography the procedure can be used on a preparati