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Proton-coupled electron transfer in[(bpy)2Mn(O)2Mn(bpy)2]3+: Role of the electrode surface

โœ Scribed by H.Holden Thorp; Gary W. Brudvig; Edmond F. Bowden


Publisher
Elsevier Science
Year
1990
Weight
503 KB
Volume
290
Category
Article
ISSN
0022-0728

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The structures, properties, and the electron transfer reactivities of Mn 2+ (H 2 O) 2 /Mn 3+ (H 2 O) 2 have been investigated in this article at the different levels of theory. The geometrical optimizations that have been made at the UMP2(full)/6-311+G \* level for these two species, the binding cha