## Abstract The kinetics of butyl acrylate solution polymerization up to high conversion are studied both experimentally and theoretically. New expressions taking into account both inter‐ and intra‐molecular transfer to polymer are derived for polymerization rate, average chain‐length and branching
The Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates
✍ Scribed by Nikitin, Anatoly N.; Hutchinson, Robin A.
- Book ID
- 115545836
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 213 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A penultimate model of acrylate polymerization has been proposed to account for reduced reactivity of radicals formed by monomer addition to midchain radicals. New expressions derived for polymerization rate, number‐average degree of polymerization and branching level are used for a com
## Abstract **Summary:** Procedures are developed to estimate kinetic rate coefficients from available rate data for the free radical solution polymerization of butyl acrylate at 50 °C. The analysis is based upon a complete mechanistic set that includes the formation of mid‐chain radicals through b
## Abstract Pulsed‐laser polymerization (PLP) has been adopted by IUPAC as the method of choice for the determination of propagation rate constants (__k__~p~). However, the method has failed in the polymerization of alkyl acrylates at temperatures above 30 °C. In this work, the PLP experiments were
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