𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of Intramolecular Transfer to Polymer on Stationary Free-Radical Polymerization of Alkyl Acrylates, 5 – Consideration of Solution Polymerization up to High Temperatures

✍ Scribed by Anatoly N. Nikitin; Robin A. Hutchinson; Wei Wang; George A. Kalfas; John R. Richards; Christopher Bruni

Book ID
112147248
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
372 KB
Volume
4
Category
Article
ISSN
1862-832X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The Effect of Intramolecular Transfer to
The Effect of Intramolecular Transfer to Polymer on Stationary Free-Radical Polymerization of Alkyl Acrylates, 3 – Consideration of Solution Polymerization up to High Conversions
✍ Anatoly N. Nikitin; Robin A. Hutchinson; George A. Kalfas; John R. Richards; Chr 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 361 KB 👁 1 views

## Abstract The kinetics of butyl acrylate solution polymerization up to high conversion are studied both experimentally and theoretically. New expressions taking into account both inter‐ and intra‐molecular transfer to polymer are derived for polymerization rate, average chain‐length and branching

Effect of Intramolecular Transfer to Pol
Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 4 - Consideration of Penultimate Effect
✍ Anatoly N. Nikitin; Robin A. Hutchinson 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 283 KB

## Abstract A penultimate model of acrylate polymerization has been proposed to account for reduced reactivity of radicals formed by monomer addition to midchain radicals. New expressions derived for polymerization rate, number‐average degree of polymerization and branching level are used for a com

Effect of Intramolecular Transfer to Pol
Effect of Intramolecular Transfer to Polymer on Stationary Free Radical Polymerization of Alkyl Acrylates, 2 : Improved Consideration of Termination
✍ Anatoly N. Nikitin; Robin A. Hutchinson 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract **Summary:** Procedures are developed to estimate kinetic rate coefficients from available rate data for the free radical solution polymerization of butyl acrylate at 50 °C. The analysis is based upon a complete mechanistic set that includes the formation of mid‐chain radicals through b