Cationic micelles of cetyltrimethylammonium bromide, CTABr, speed attack of hydroxide ion upon coumarin by a factor of c.a-2, due to a concentration effect. The first-order rate constants, at a given hydroxide ions concentration go through maxima with increasing k , obs surfactant concentration. The
The effect of electrochemical regeneration upon the enzymatic catalysis of a thermodynamically unfavorable reaction
โ Scribed by Jean Marc Laval; Jacques Moiroux; Christan Bourdillon
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 866 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0006-3592
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## Abstract Attention is drawn to the feasibility of using isothermal calorimetry for the characterization of enzyme reactions under conditions bearing greater relevance to the crowded biological environment, where kinetic parameters are likely to differ significantly from those obtained by classic