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The effect of a magnetic field on outer-sphere electron transfer

✍ Scribed by A.I. Ivanov; V.A. Mikhaylova

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
355 KB
Volume
212
Category
Article
ISSN
0009-2614

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✦ Synopsis

The magnetic field influence on the outer-sphere electron transfer rate is analyzed within the framework of a dynamical model including exchange interaction between the transferred electron and a paramagnetic centre placed in the vicinity of an acceptor. It is shown that the rate can vary by 20%-30%. In the investigated range of the parameters the magnetic field effect is negligible in both the adiabatic and the nonadiabatic limits and can be observed only in the transitional region.

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