The aontinuou interest in the area of the biaplo[3~1.0]hex+2-on-'tyl aatlsnbl) prompted ua to investigate the aorre~ndlng benseblayala eyrtem. Thi?, work roporta same resulte an the aol~olyeer of 4-ahlcm-banm[&]blayalo
The effect of 1,5-bridging on the solvolytic behavior of the bicyclo[3.1.0]hex-2-yl cation
โ Scribed by Paul G. Gassman; Richard N. Steppel; Eugene A. Armour
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 200 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The generation of the bicyclo[3.l.O]hex-2-yl cation has been the subject of much recent discussion.
2
In particular, considerable attention has been given to the question of whether
๐ SIMILAR VOLUMES
Below -60' in FSOaH/SOzClF the nonamethyl bicyclo[3.2.1 loctadien-Pyl cation J, undergoes two degenerate rearrangements, circumambulation' and a 1,2-shift of the methano bridge.2 The first of these processes is much faster than the second, and is nmr-observable,' whereas the second process was detec
Anions of allylmeldrum's acids reacted with phenyl(propynyl)iodonium salt to produce bicyclo[3.1.0]hex-1-enes as the reactive intermediates through cyclopropanation reaction to yield various dimerization products. Depending on the substitution pattern on the intermediates, various dimeric products w
In FSOsH/SO&lF at -50 to -100' the nonamethylbicyclo[3.2.1] octadien-2-yl cation 1 undergoes an nmr-observable reversible exchange process which equilibrates methyls 2,3,4,6 and 7 and methyls 8 and 9, but leaves the bridgehead methyls (1 and 5) unique.l CIRCUMAMBULATION 3 This observation was ration
The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that