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Effect of substitution and temperature on the reactivity of bicyclo[3.1.0]hex-1-ene system

✍ Scribed by Hee-Yoon Lee; Yeonjoon Kim; Yong-Han Lee; Byung Gyu Kim

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
67 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Anions of allylmeldrum's acids reacted with phenyl(propynyl)iodonium salt to produce bicyclo[3.1.0]hex-1-enes as the reactive intermediates through cyclopropanation reaction to yield various dimerization products. Depending on the substitution pattern on the intermediates, various dimeric products were obtained.

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